Category EV L19 An Alternative Pathway For Waste Streams

Abstract The purpose of this project is to produce biochar from what one would

consider waste Phragmities, Cherries, and Orange Peels, determine if the

biochar produces a more environmentally friendly water runoff than

fertilizer, determine if the plant fertilizer effects soil quality, determine if

change in temperature during pyrolysis effects the Biochar’s porosity, and

determine if change in temperature during pyrolysis effects the Syngases

produced. Biochar will have a more environmentally friendly effect on

amending the soils. Also, the amount of nitrogen, potassium, and

phosphorus will vary with the biowaste. Varying the temperature during

pyrolysis different gases will be produced as well as a change in porosity

in the biochar. The elemental analysis of the samples with Biochar added

shows that the soils were amended by the addition of the biochar.

However, the fertilizer didn’t amend the quality of the soils over time. For

the most part all of the samples had a pH within the optimal range pH 5.8-

7.0; however five samples had values below the optimal range

(Clay/Fertilizer, Top Soil/Cherry Biochar, Sand/Cherry Biochar, Top

Soil/Orange Biochar, and Top Soil/Fertilizer). It is known that fertilizer make

soils acidic. The Boiling point of all of the Biofuels synthesized were above

208 oF. With the Biofuel of cherries (500oF) showing peaks at 240oC.

The 900oF Phragmities showed peaks in the C14 hydrocarbon which has

a retention time of approximately 8 minutes. Whereas the other Biofuels

had an elution time of only two minutes. Also in some cases as

temperature increased to 900oF peaks decreased. The highest amounts of

Nitrate were found in Clay/Control, Clay/Orange Biochar, and Top

Soil/Cherry Biochar. The lowest amounts of Nitrate were found in

Clay/Phragmities Biochar which contained 1.034 mg/L. Cherries yielded the

highest amount of organics among the 3 starting materials. Cherries at 900

oF contained approximately 31.4% of organics. The organic oil can be

potentially recovered and can be used as renewable chemical feedstock

or fuel.

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